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Chemistry 2720 Fall 1999 Quiz 7 Solution

Since HI is a strong acid, it completely dissociates in water. However, because the concentration is so low, we must consider the water autoionization equilibrium. The reaction is

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For this reaction

eqnarray12

The equilibrium constant is related to the activities by

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The charge balance equation for this solution is

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with tex2html_wrap_inline77 . Combining these last two equations, we have

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which we can rearrange to the quadratic equation

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The positive root of this equation is

eqnarray46



Marc Roussel
Thu Nov 4 11:53:56 MST 1999