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Chemistry 2710 Spring 2000 Quiz 2 solution

The order with respect to C is easiest to determine: The rate goes down by a factor of 10 every time the concentration of C goes down by a factor of 10 (experiments 1, 4 and 5). The rate is therefore proportional to the first power of c.

For A, consider the following table:

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Thus, the rate goes up by a factor of about 2.83 when the concentration is doubled. We are looking for a simple rate law of the form

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Ratios of rates at constant c are therefore related by

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By taking logarithms of both sides of this equation, we get

eqnarray18

The rate law is therefore

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The rate constant can be found using the data from any of the experiments. For instance, using experiment 1, we get

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Marc Roussel
Sat Jan 22 20:23:26 MST 2000