next
Up: Back to the Chemistry 2710 assignment index

Chemistry 2710 Review Problem for the March 3-5 Lectures

We have been studying the reaction

displaymath24

Suppose that the rate constants can be estimated from experimental data (they can, from experiments to be discussed later) and that their values are, approximately, tex2html_wrap_inline26 , tex2html_wrap_inline28 and tex2html_wrap_inline30 . Is it appropriate to use either the equilibrium or steady-state approximation? Why? If tex2html_wrap_inline32 , roughly what is the value of b after the induction period but before significant amounts of product have accumulated? What is the initial rate? Further suppose that we want a maximum of 1% of the A initially present to react during the initial rate experiment. Roughly how long should we allow the reaction to proceed?


Marc Roussel
Mon Mar 6 14:22:37 MST 2000