Publications
(a) Journal Articles
J. P. Mack, J. A. Boatz, M. Gerken
"Synthesis, NMR and vibrational
spectroscopic characterization, and computational study of the cis-IO2F32-
anion"
Inorganic Chemistry 2008,
47,
3243-3247.
M. Gerken, P. Hazendonk, A. Iuga,
J. Nieboer, M. Tramsek, E. Goreshnik, B. Zemva, S. Zheng, J. Autschbach
"Solid-state NMR spectroscopic
study of coordination compounds of XeF2 with metal cations and
the crystal structure of
[Ba(XeF2)5][AsF6]2"
Inorganic Chemistry 2007,
46,
6069-6077.
A. Iuga, D. Iuga, A. Cross, M.
Gerken, P. Hazendonk
"Observation of satellite signals
due to scalar coupling to spin-1/2 isotopes in solid-state nuclear magnetic
resonance spectroscopy"
Journal of Chemical Physics2007,
126, 054305/1-054305/10.
M. A. M. Forgeron, R. E. Wasylishen,
M. Gerken, G. J. Schrobilgen
"Solid-state 129Xe
and 131Xe NMR study of the perxenate anion XeO64-"
Inorganic Chemistry 2007,
46,
3585-3592.
S. Schneider, M. Gerken, R. Haiges,
T. Schroer, J. A. Boatz, D. A. Dixon, D. J. Grant, K. O. Christe
"Synthesis and Characterization
of Silyldichloramines, their Reactions with F- Ions, instability
of N2Cl2 and NCl2-, and Formation
of NCl3"
Inorganic Chemistry 2007,
46,
93-102.
M. Gerken, P. Hazendonk, A. Iuga,
J. P. Mack, H. P. A. Mercier, G. J. Schrobilgen
"The solid-state 19F
NMR spectrum of [N(CH3)4][IO2F2],
a vibrational study of [N(CH3)4][IO3]
and [N(CH3)4][IO3]•2H2O, and the X-ray
crystal
structures of [N(CH3)4][IO2F2]
and [N(CH3)4][IO3]"
Journal of Fluorine Chemistry
2006, 127, 1328-1338.
R. Haiges, M. Gerken, A. Iuga,
R. Bau, K. O. Christe
"Are the NF4+
Cations in NF4BF4 Really Nontetrahedral?"
Inorganic Chemistry 2006,45,
7981-7984.
R. Haiges, J. A. Boatz, A. Vij,
V. Vij, M. Gerken, S. Schneider, T. Schroer, M. Yousufuddin, K. O. Christe
"Polyazide Chemistry. Preparation
and Characterization of As(N3)5, Sb(N3)5,
and [P(C6H5)4][Sb(N3)6]"
Angewandte Chemie, 2004,
116,
6844-6848; Angewandte Chemie, International Edition, English2004,
43, 6676-6680.
M. Gerken, J. P. Mack, G. J. Schrobilgen,
R. J. Suontamo
"Synthesis, vibrational and NMR
spectroscopic characterization of [N(CH3)4][IO2F2]
and X-ray crystal structure of [N(CH3)4]2[IO2F2][HF2]"
Journal of Fluorine Chemistry,
2004,
125, 1663-1670.
M. Gerken, P. Hazendonk, J. Nieboer,
G. J. Schrobilgen
"NMR spectroscopic study of xenon
fluorides in the gas phase and of XeF2 in the solid state"
Journal of Fluorine Chemistry,
2004,
125,
1163-1168.
A. Vij, W. W. Wilson, V. Vij,
R. Corley, F. S. Tham, M. Gerken, R. Haiges, S. Schneider, T. Schroer,
R. I. Wagner
"Methyl Tin(IV) Derivatives of
HOTeF5 and HN(SO2CF3)2: A Solution
Multinuclear NMR Study and X-ray Crystal Structures of
(CH3)2SnCl(OTeF5)
and [(CH3)3Sn(H2O)2][N(SO2CF3)2]"
Inorganic Chemistry, 2004,
43,
3189-3199.
R. Haiges A. Vij, J. A. Boatz,
S. Schneider, T. Schroer, M. Gerken, K. O. Christe
"First Structural Characterization
of Binary As(III) and Sb(III) Azides"
Chemistry, A European Journal,
2004,
10,
508-517.
R. Haiges, J. A. Boatz, A. Vij,
M. Gerken, S. Schneider, T. Schroer, K. O. Christe
"Polyazide Chemistry. Preparation
and Characterization of Te(N3)4 and [P(C6H5)4]2[Te(N3)6]
and Evidence for [N(CH3)4]2[Te(N3)5]
"
Angewandte Chemie, 2003,
115,
6027-6031.
J. A. Boatz, K. O. Christe, D.
A. Dixon, B. A. Fir, M. Gerken, R. Z. Gnann, H. P. A. Mercier, and
G. J. Schrobilgen
"Synthesis and Characterization
of the trans-IO2F52- Dianion"
Inorganic Chemistry, 2003,
42,
5282-5292.
K. O. Christe, M.Gerken, R. Haiges,
S. Schneider, T. Schroer, I. Tsyba, R. Bau
"The (SO2)2N3-
Anion"
Inorganic Chemistry, 2003,
42,
416-419.
K. O. Christe, M.Gerken, R. Haiges,
S. Schneider, T. Schroer, F. S. Tham, A. Vij
"Tritylsulfinylamine: A New Member
in the Family of Sulfinylamines."
Solid State Sciences,
2002,
4,
1529-1534.
K. O. Christe, J. A. Boatz,
M. Gerken, R. Haiges, S. Schneider, T. Schroer, F. S. Tham, A. Vij, V.
Vij, R. I. Wagner, and W. W. Wilson
"Synthesis and Characterization
of the SO2N3-, (SO2)2N3-,
and SO3N3- Anions"
Inorganic Chemistry, 2002,
41,
4275-4285.
M. Gerken, J. A. Boatz, A. Kornath,
R. Haiges, S. Schneider, T. Schroer, K. O. Christe
"The 19F NMR Shifts are not a
Measure for the Nakedness of the Fluoride Anion"
Journal of Fluorine Chemistry,
2002,
116,
49-58.
K. O. Christe, M. Gerken, S. Schneider,
T. Schroer
"Improved Synthesis of CsN3"
Zeitschrift für allgemeine
und anorganische Chemie, 2002, 628, 909-910.
M. Gerken, D. A. Dixon, G. J.
Schrobilgen
"The OsO3F+
and Os2O6F3+ Cations, Their
Syntheses and Study by Raman and 19F NMR Spectroscopy and Electron
Structure Calculations;
and the X-ray Crystal Structures
of [OsO3F][PnF6] (Pn = As, Sb), [OsO3F][HF]2[AsF6],
[OsO3F][HF][SbF6], and [OsO3F][Sb3F16]"
Inorganic Chemistry, 2002,
41,
259-277.
M. Gerken and G. J. Schrobilgen
"Solution Multi-NMR and Raman
Spectroscopic Study of Thermodynamically Unstable XeO4; the First 131Xe
NMR Study of a Chemically
Bound Xenon Species "
Inorganic Chemistry, 2002,
41, 198-204.
B. Fir, M. Gerken, B. E. Pointner,
H. P. A. Mercier, D. A. Dixon, G. J. Schrobilgen
"An X-ray Crystallographic Study
of [Xe2F3][SbF6] and Dimorphism in [Xe2F3][SbF6]"
Journal of Fluorine Chemistry,
2000,
105,
159-167.
M. Gerken, D. A. Dixon, G. J.
Schrobilgen
"The OsO4F-,
OsO4F22-, and OsO3F3-
Anions and Their Study by Vibrational and NMR Spectroscopy and Density
Functional Calculations;
and the X-ray Crystal Structures
of [N(CH3)4][OsO4F] and [N(CH3)4][OsO3F3]"
Inorganic Chemistry, 2000,
39,
4244-4255.
M. Gerken, P. Kolb, A. Wegner,
H. P. A. Mercier, H. Borrmann, D. A. Dixon, G. J. Schrobilgen
"Tetrachloro- and tetrabromoarsonium(V)
Cations: Raman and 75As, 19F NMR Spectroscopic Characterization
and X-ray Crystal Structures
of AsCl4+
As(OTeF5)6- and AsBr4+
AsF(OTeF5)5-"
Inorganic Chemistry, 2000,
39,
2813-2824.
J. Campbell, L. A. Devereux, M.
Gerken, H. P. A. Mercier, A. M. Pirani, G. J. Schrobilgen
"Ditin(IV) Chalcogenide Anions:
77Se,
119Sn
and 125Te Solution NMR Study of the Sn2Ch64-
and Sn2Ch74- (Ch = Se, Te), X-Ray Crystal
Structures and Raman Spectra
of K+(N(CH3)4+)3Sn2Se64-,
(enH+)2(2,2,2-crypt-K+)2Sn
2Se64-,
(K+)2(2,2,2-crypt-K+)2Sn2Te64-
and X-Ray
Crystal Structures of K+(2,2,2-crypt-K+)2HOSnTe33-
and K+(2,2,2-crypt-K+)2HOSnTe33-
en."
Inorganic Chemistry, 1996,
35,
2945-2962.
(b) Contributions to Books
M. Gerken, G. J. Schrobilgen
"Osmium(VIII) Oxide and Oxide
Fluoride Chemistry"
In Inorganic Chemistry Highlights;
G. Meyer, D. Naumann, L. Wesemann, Eds.; Wiley-VCH, 2005, 243-266.
M. Gerken, H. P. A. Mercier, G.
J. Schrobilgen
"Syntheses and Structures of
the Oxide Fluorides of the Main-Group and Transition Metal Elements"
In Advanced Inorganic Fluorides:
Synthesis, Characterization and Application; T. Nakajima, A. Tressaud,
B. Zemva, eds., Elsevier Science,
1999, 117 - 174.
(c) Review Articles
M. Gerken, G. J. Schrobilgen
"The Impact of Multi-NMR Spectroscopy
on the Development of Noble-Gas Chemistry."
Coordination Chemistry Reviews,
2000,
197,
335-395.